Preheat the oven to 350°F. Mix 2 tbsp softened butter and 1 tbsp cocoa powder and brush the inside of a bundt pan with a pastry brush. Set aside.
In a mixing bowl, add 1 ¾ cups all-purpose flour, 1 tsp baking soda, and ¼ tsp salt. Whisk and set aside.
In a separate bowl, add 6 ounces chopped semisweet chocolate, ¾ cup natural cocoa powder, and 1 tsp instant espresso powder. Pour over ¾ cup boiling water, whisk until the chocolate is melted and the mixture is smooth. Then set aside to cool off.
In a separate large mixing bowl, add 12 tbsp room temperature unsalted butter and 1 ½ cups granulated sugar. Using a stand or hand mixer, beat everything together on a high speed for 3-5 minutes, or until it’s light and airy.
Add 5 room temperature eggs (1 egg at a time) and beat well again.
Add 1 tsp vanilla extract and 1 cup room temperature sour cream. Mix well until combined.
Then add the chocolate mixture and mix until combined.
Add dry ingredients and fold them in until there are no flour pockets.
Pour the batter into the pre-greased Bundt pan, transfer to the oven and bake at 350°F for about 45 minutes.
To make sure it’s properly baked, insert a toothpick in the center, it should come out with moist crumbs but not wet.
Take the pan out of the oven and let sit on the counter for 10 minutes. Then flip the pan and transfer the cake to a wire rack. Let it cool off completely for about 2 hours.
Chop 4 ounces chocolate in smaller pieces and transfer to a bowl.
Heat up ½ cup heavy cream in a saucepan over medium heat until light simmer. Then pour over the chopped chocolate and let sit for 2-3 minutes.
Whisk very well until all the chocolate is melted and the ganache is smooth consistency.
Let it sit on the countertop until it cools off and gets thicker consistency.
When ready to serve, drizzle over the cake and let it drip on the sides.